Ni-MH Rechargeable Batteries T able of Contents 1 Introduction 2 General Characteristics 3 Composition and Chemistry 3.1 Active Components: Positive and Negative Electrodes 3.2 Electrolyte 3.3 Cell Reactions 4 Battery Construction 4.1 Basic Cell Construction 4.2 Cylindrical Cell Construction 4.3 Prismatic Cell Construction 5 Performance Characteristics 5.1 General Characteristics 5.2 Discharge Characteristics: Effect of Discharge Rate and Temperature 5.
Ni-MH Rechargeable Batteries 1 Introduction Rapid advancements in electronic technology have expanded the number of battery-powered portable devices in recent years, stimulating consumer demand for higher-energy rechargeable batteries capable of delivering longer service between recharges or battery replacement.
Ni-MH Rechargeable Batteries Composition and Chemistry A rechargeable battery is based on the principle that the charge/discharge process is reversible, that is, the energy delivered by the battery during discharge can be replaced or restored by recharging. 3.1 Active Components: Positive and Negative Electrodes Nickel oxyhydroxide (NiOOH) is the active material in the positive electrode of the nickel-metal hydride battery in the charged state, the same as in the nickelcadmium battery.
Ni-MH Rechargeable Batteries Composition and Chemistry (cont.) The sealed nickel-metal hydride cell uses the “oxygen-recombination” mechanism to prevent a buildup of pressure that may result from the generation of oxygen towards the end of charge and overcharge. This mechanism requires the use of a negative electrode (the metal hydride /metal electrode) which has a higher effective capacity than the positive (nickel oxyhydroxide/nickel hydroxide electrode) electrode.
4 Ni-MH Rechargeable Batteries Battery Construction DURACELL standard-sized nickel-metal hydride batteries are constructed with cylindrical and prismatic nickelmetal hydride cells. DURACELL nickel-metal hydride batteries are a sealed construction designed for optimal performance and maximum safety.
Ni-MH Rechargeable Batteries Battery Construction (cont.) 4.3 Prismatic Cell Construction The basic differences between the prismatic cell and the cylindrical cell are the construction of the electrodes and the shape of the can. Prismatic cells are designed to meet the needs of compact equipment where space for the battery is limited. The rectangular shape of the prismatic cell permits more efficient battery assembly by eliminating the voids that occur in a battery constructed with cylindrical cells.
5 Ni-MH Rechargeable Batteries Performance Characteristics FIGURE 5.2.1 5.1 General Characteristics 8.5 Temperature: 45°C (113°F) Voltage (V) 8.0 FIGURE 5.1.1 C/5 (0.48A) C (2.4A) 7.0 6.0 5.5 0 0.5 1.0 1.5 Discharge Capacity (Ah) 2.0 2.5 FIGURE 5.2.2 8.5 Temperature: 21°C (70°F) 8.0 1.5 1.4 Voltage (V) 7.5 6.5 Voltage (V) The discharge characteristics of the nickel-metal hydride cell are very similar to those of the nickelcadmium cell.
Ni-MH Rechargeable Batteries Performance Characteristics (cont.) 5.3 Capacity: Effect of Discharge Rate and Temperature The ampere-hour capacity of the battery is dependent on the discharge current and temperature, as can be observed in Figure 5.3.1. It should be noted that the delivered capacity is dependent on the cutoff or end voltage. The delivered capacity can be increased by continuing the discharge to lower end voltages.
Ni-MH Rechargeable Batteries Performance Characteristics (cont.) Figure 5.4.1 compares the gravimetric and volumetric energy density of nickel-metal hydride and nickel-cadmium cells. As indicated, nickel-metal hydride cells deliver more energy per weight or volume than nickel-cadmium cells. FIGURE 5.4.1 200 Wh/L 150 Wh/L 100 5.
Ni-MH Rechargeable Batteries Performance Characteristics (cont.) FIGURE 5.7.1 DURACELL nickel-metal hydride batteries have low internal impedance because they are manufactured using cells designed with thin plate electrodes which offer large surface areas and good conductivity. Figure 5.7.1 shows the change in internal impedance with depth of discharge. As demonstrated, the impedance remains relatively constant during most of the discharge.
Ni-MH Rechargeable Batteries Performance Characteristics (cont.) 5.9 Voltage Depression (“Memory Effect”) 1.35 1.25 Voltage (V) Although many years of premium performance can be enjoyed from a nickel-metal hydride battery that is properly handled, the capacity delivered in each charge/discharge cycle will eventually begin to decrease. This inevitable decrease in capacity can be accelerated by overcharging, storage or usage at high temperatures, or through poor matching of cells within a pack.
6 Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries 6.1 General Principles 2.0 Voltage /Cell (V) Recharging is the process of replacing energy that has been discharged from the battery. The subsequent performance of the battery, as well as its overall life, is dependent on effective charging. The main criteria for effective charging are: FIGURE 6.1.1 • Choosing the appropriate rate 1.6 1.2 1.0 • Selecting the appropriate termination technique 11 Ni-MH 1.
Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries (cont.) 6.2 Techniques for Charge Control The characteristics of the nickel-metal hydride battery define the need for proper charge control in order to terminate the charge and prevent overcharging or exposure to high temperatures. Each charge control technique has its advantages and disadvantages.
Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries (cont.) The following summary explains some of the recommended methods for charge control. The characteristics of each of these methods are illustrated in Figure 6.2.1. In many cases, several methods are employed, particularly for high rate charging. Voltage drop is widely used with nickel-cadmium batteries. With this technique, the voltage during charge is monitored and the charge is terminated when the voltage begins to decrease.
Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries (cont.) 6.2.4 Temperature Cutoff (cont.) Usually this method is used in conjunction with other charge control techniques primarily to terminate the charge in the event that the battery reaches excessive temperatures before the other charge controls activate. A charge rate of 1C and a temperature cutoff at 60°C (140°F) is recommended. A top-up charge is not recommended if this termination method is used. 6.2.
Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries (cont.) 6.3.1 Duracell’s Recommendation: Three-Step Charge Procedure For fast charging and optimum performance, Duracell recommends a three-step procedure that provides a means of rapidly charging a nickel-metal hydride battery to full charge without excessive overcharging or exposure to high temperatures. The steps in sequential order are: 1) Charge at the 1C rate, terminated by using dT/dt = 1°C (1.8°F ) /minute.
Ni-MH Rechargeable Batteries Charging Sealed Nickel-Metal Hydride Batteries (cont.) 6.3.5 Trickle Charge A number of applications require the use of batteries which are maintained in a fully-charged state. This is accomplished by trickle charging at a rate that will replace the loss in capacity due to self-discharge. In these applications, a trickle charge at a C/300 rate is recommended. The preferred temperature range for trickle charging is between 10°C to 35°C (50°F to 95°F).
7 Ni-MH Rechargeable Batteries Cycle and Battery Life 7.1 Cycle Life FIGURE 7.1.1 The cycle life of nickel-metal hydride batteries depends on the many conditions to which the battery has been exposed, as is true for all types of rechargeable batteries.
Ni-MH Rechargeable Batteries Cycle and Battery Life (cont.) Charge rate and amount of charge input during overcharging are also important factors affecting cycle life. If the battery is charged at a rate that exceeds the oxygen recombination rate, oxygen that is generated during overcharge will not react, causing a build up in gas pressure and a rise in temperature which will have damaging effects on battery and cycle life.
8 Ni-MH Rechargeable Batteries Safety Considerations Duracell’s nickel-metal hydride batteries are designed to ensure maximum safety. Each cell includes a resealable pressure relief mechanism (safety vent) to prevent excessive build-up of pressure in the cell in the event it is overcharged excessively, exposed to extreme high temperatures, or otherwise abused. Duracell’s nickel-metal hydride batteries contain protective devices, as discussed in Section 6.
Ni-MH Rechargeable Batteries Safety Considerations (cont.) Table 8.0.1 Test Test Conditions Test Results Flat Plate Crush Test Cell is crushed between two flat surfaces. No explosion, sparks, or flames. Impact Test A 20 lb. weight is dropped from height of 2 feet on cell. No explosion, sparks, or flames. Short Circuit Test* Sample is shorted until discharged. Test conducted at 20°C and 60°C (68°F and 140°F). No evidence of venting, leakage, bulging or other visible changes on individual cells.
9 Ni-MH Rechargeable Batteries Proper Use and Handling Nickel-metal hydride batteries can give years of safe and reliable service if they are used in accordance with recommended procedures and are not abused. The batteries can be used in any operating position. Other than charging, the only maintenance that should be required is to keep them clean and dry both during use and storage.
Ni-MH Rechargeable Batteries Proper Use and Handling (cont.) 9.2 Transportation Procedures for the transportation of batteries are specified by the United States Department of Transportation in the “Code of Federal Regulations,” CFR49, entitled “Transportation.” Internationally, air transportation is specified by the International Civil Aviation Organization (ICAO) in their publication “Technical Instructions for the Safe Transport of Dangerous Goods By Air.