Version: 1.1 Revision Date: 02/20/2019 SAFETY DATA SHEET 1. Identification Material name: VULKEM 45 SSL LIMESTONE Material: 445805 333 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2.
Version: 1.1 Revision Date: 02/20/2019 Hazard Symbol: Signal Word: Danger Hazard Statement: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause cancer. May damage fertility or the unborn child. Toxic to aquatic life. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. [In case of inadequate ventilation] wear respiratory protection.
Version: 1.1 Revision Date: 02/20/2019 Butyl benzyl phthalate 85-68-7 10 - <25% Calcium Carbonate (Limestone) 1317-65-3 10 - <20% Polyvinyl chloride 9002-86-2 10 - <20% Petroleum distillates 64742-47-8 1 - <5% Aliphatic naphtha 64742-88-7 1 - <5% Xylene 1330-20-7 1 - <5% Calcium oxide 1305-78-8 1 - <5% Titanium dioxide 13463-67-7 1 - <5% Diisodecyl phthalate 26761-40-0 0.1 - <1% Ethylbenzene 100-41-4 0.1 - <1% Isophorone Diisocyanate 4098-71-9 0.
Version: 1.1 Revision Date: 02/20/2019 Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media: Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical: During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available.
Version: 1.1 Revision Date: 02/20/2019 Control Parameters Occupational Exposure Limits Chemical Identity Type Calcium Carbonate (Limestone) - Total dust. Calcium Carbonate (Limestone) - Respirable fraction. Polyvinyl chloride Respirable fraction. Polyvinyl chloride - as vinyl chloride monomer PEL 15 mg/m3 PEL 5 mg/m3 TWA 1 mg/m3 Polyvinyl chloride Respirable fraction. Polyvinyl chloride - Total dust. Exposure Limit Values TWA 1 ppm STEL 5 ppm OSHA_AC T PEL 0.
Version: 1.1 Revision Date: 02/20/2019 AN ESL 42 ppb AN ESL 180 µg/m3 STEL 150 ppm Ceiling 300 ppm TWA PEL 100 ppm TWA 100 ppm STEL 150 ppm PEL 100 ppm 655 mg/m3 435 mg/m3 US. ACGIH Threshold Limit Values (2011) 435 mg/m3 Calcium oxide TWA PEL 2 mg/m3 5 mg/m3 Titanium dioxide Titanium dioxide - Total dust. TWA PEL 10 mg/m3 15 mg/m3 Titanium dioxide - Respirable fraction. TWA Titanium dioxide - Total dust.
Version: 1.1 Revision Date: 02/20/2019 Chemical name Type Exposure Limit Values Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 TWA 10 mg/m3 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyvinyl chloride Respirable. TWA 1 mg/m3 Polyvinyl chloride Respirable fraction. Polyvinyl chloride - Total dust.
Version: 1.1 Revision Date: 02/20/2019 Xylene STEL 150 ppm 651 mg/m3 TWA 100 ppm 434 mg/m3 Titanium dioxide - Total dust. TWA 10 mg/m3 Titanium dioxide - Respirable fraction. TWA 3 mg/m3 Titanium dioxide TWA 10 mg/m3 Titanium dioxide - Total dust. TWA 10 mg/m3 Ethylbenzene TWA 20 ppm Ethylbenzene TWA 20 ppm Ethylbenzene STEL 125 ppm 543 mg/m3 TWA 100 ppm 434 mg/m3 TWA 0.005 ppm Isophorone Diisocyanate CEILING Isophorone Diisocyanate 0.01 ppm TWA 0.005 ppm CEV 0.
Version: 1.1 Revision Date: 02/20/2019 1,2,4-Trimethylbenzene TWA 25 ppm 123 mg/m3 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm Chemical name Type Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 TWA 10 mg/m3 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyvinyl chloride Respirable. TWA 1 mg/m3 Polyvinyl chloride Respirable fraction.
Version: 1.1 Revision Date: 02/20/2019 Xylene Xylene Xylene TWA 100 ppm STEL 150 ppm TWA 100 ppm STEL 150 ppm STEL 150 ppm 651 mg/m3 TWA 100 ppm 434 mg/m3 Calcium oxide TWA 2 mg/m3 Calcium oxide TWA 2 mg/m3 Calcium oxide TWA 2 mg/m3 Titanium dioxide - Total dust. TWA 10 mg/m3 Titanium dioxide - Respirable fraction. TWA 3 mg/m3 Titanium dioxide TWA 10 mg/m3 Titanium dioxide - Total dust.
Version: 1.1 Revision Date: 02/20/2019 Isophorone Diisocyanate TWA 0.005 ppm 0.045 mg/m3 Hydrotreated heavy naphthenic distillate - Mist. TWA 0.2 mg/m3 TWA 1 mg/m3 TWA 5 mg/m3 TWA 5 mg/m3 STEL 10 mg/m3 TWA 5 mg/m3 Hydrotreated heavy naphthenic distillate Inhalable fraction. Hydrotreated heavy naphthenic distillate - Mist. Canada. Quebec OELs. (Ministry of Labor Regulation Respecting the Quality of the Work Environment) (09 2017) Canada. British Columbia OELs.
Version: 1.1 Revision Date: 02/20/2019 Talc - Respirable. TWA 2 mg/m3 Talc - Respirable dust. TWA 3 mg/m3 Talc TWA 2 Fibers/cc Talc - Respirable fraction. TWA 2 mg/m3 Nonane TWA 200 ppm Nonane TWA 200 ppm Nonane TWA 200 ppm 1,050 mg/m3 Aluminum oxide - Respirable. TWA 1 mg/m3 Aluminum oxide - Total dust. TWA 10 mg/m3 Aluminum oxide - Respirable fraction. TWA 3 mg/m3 Aluminum oxide - Respirable fraction. Aluminum oxide - Inhalable fraction. Aluminum oxide - Respirable fraction.
Version: 1.1 Revision Date: 02/20/2019 Zirconium dioxide - as Zr Zirconium dioxide - as Zr TWA 5 mg/m3 STEL 10 mg/m3 TWA 5 mg/m3 STEL 10 mg/m3 Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. Quebec OELs.
Version: 1.1 Revision Date: 02/20/2019 Carbon Black - Inhalable TWA 3 mg/m3 Carbon Black - Inhalable fraction. Carbon Black TWA 3 mg/m3 TWA 3.5 mg/m3 Toluene TWA 20 ppm Toluene TWA 20 ppm Toluene TWA 50 ppm 188 mg/m3 1,2,4-Trimethylbenzene TWA 25 ppm 123 mg/m3 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 1,2,4-Trimethylbenzene TWA 25 ppm Iron oxide - Total dust. TWA 10 mg/m3 Iron oxide - Dust. - as Fe TWA 5 mg/m3 Iron oxide - Fume.
Version: 1.1 Revision Date: 02/20/2019 Cumene TWA 50 ppm Cumene TWA 50 ppm Benzene STEL 2.5 ppm TWA 0.5 ppm TWA 0.5 ppm STEL 2.5 ppm TWA 1 ppm 3 mg/m3 STEL 5 ppm 15.5 mg/m3 STEL 15 ppm TWA 10 ppm Naphthalene TWA 10 ppm Naphthalene TWA 10 ppm 52 mg/m3 STEL 15 ppm 79 mg/m3 STEL 250 ppm TWA 200 ppm STEL 250 ppm TWA 200 ppm STEL 250 ppm 328 mg/m3 TWA 200 ppm 262 mg/m3 Benzene Benzene Naphthalene Methanol Methanol Methanol 246 mg/m3 Canada. Ontario OELs.
Version: 1.1 Revision Date: 02/20/2019 Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. TWA 0.025 mg/m3 Crystalline Silica (Quartz)/ Silica Sand - Respirable fraction. Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. TWA 0.10 mg/m3 TWA 0.
Version: 1.1 Revision Date: 02/20/2019 Sampling time: End of shift.) Ethylbenzene (Sum of mandelic acid and phenylglyoxylic acid: Sampling time: End of shift.) Appropriate Engineering Controls 0.15 g/g (Creatinine in urine) ACGIH BEI (02 2014) Mechanical ventilation or local exhaust ventilation may be required. Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust.
Version: 1.1 Revision Date: 02/20/2019 Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Relative density: Solubility(ies) Solubility in water: Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: No data available. No data available. No data available. No data available. No data available.
Version: 1.1 Revision Date: 02/20/2019 Eye contact: No data available. Ingestion: No data available. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: Specified substance(s): Butyl benzyl phthalate Not classified for acute toxicity based on available data.
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Version: 1.1 Revision Date: 02/20/2019 IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Titanium dioxide Overall evaluation: Possibly carcinogenic to humans. Ethylbenzene Overall evaluation: Possibly carcinogenic to humans. Hydrotreated heavy naphthenic distillate Overall evaluation: Not classifiable as to carcinogenicity to humans. Overall evaluation: Carcinogenic to humans. Talc Overall evaluation: Not classifiable as to carcinogenicity to humans.
Version: 1.1 Revision Date: 02/20/2019 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: Specified substance(s): Butyl benzyl phthalate No data available. LC 50 (Fathead minnow (Pimephales promelas), 96 h): 1.39 - 3.88 mg/l Mortality Petroleum distillates LC 50 (Rainbow trout,donaldson trout (Oncorhynchus mykiss), 96 h): 2.9 mg/l Mortality Xylene LC 50 (Fathead minnow (Pimephales promelas), 96 h): 13.
Version: 1.1 Revision Date: 02/20/2019 Supporting study LC 50 (Pimephales promelas, 14 d): 2.25 mg/l Experimental result, Supporting study Aliphatic naphtha NOAEL (Oncorhynchus mykiss, 28 d): 0.098 mg/l QSAR QSAR, Key study Hydrotreated heavy naphthenic distillate NOAEL (Oncorhynchus mykiss, 14 d): >= 1,000 mg/l QSAR QSAR, Supporting study Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available.
Version: 1.1 Revision Date: 02/20/2019 Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Version: 1.1 Revision Date: 02/20/2019 US. OSHA Specifically Regulated Substances (29 CFR 1910.
Version: 1.1 Revision Date: 02/20/2019 SARA 302 Extremely Hazardous Substance Reportable Chemical Identity quantity Isophorone Diisocyanate 500 lbs. Threshold Planning Quantity 500 lbs. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Butyl benzyl phthalate 100 lbs. Xylene 100 lbs. Diisodecyl phthalate Ethylbenzene 1000 lbs. Isophorone Diisocyanate Nonane 100 lbs. Dibutyl phthalate 10 lbs. Diisodecyl phthalate (mixed Is) Toluene 1000 lbs. Cumene 5000 lbs. Benzene 10 lbs.
Version: 1.1 Revision Date: 02/20/2019 Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Reportable quantity Chemical Identity Xylene Reportable quantity: lbs. US State Regulations US. California Proposition 65 WARNING Cancer and Reproductive Harm - www.P65Warnings.ca.gov US.
Version: 1.1 Revision Date: 02/20/2019 US. Rhode Island RTK Chemical Identity Calcium Carbonate (Limestone) Polyvinyl chloride Petroleum distillates Aliphatic naphtha Xylene Titanium dioxide International regulations Montreal protocol Not applicable Stockholm convention Not applicable Rotterdam convention Not applicable Kyoto protocol Not applicable VOC: Regulatory VOC (less water and exempt solvent) VOC Method 310 : 103 g/l : 7.
Version: 1.1 Revision Date: 02/20/2019 Inventory Status: Australia AICS: One or more components in this product are not listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS) List: One or more components in this product are not listed on or exempt from the Inventory. China Inv. Existing Chemical Substances: One or more components in this product are not listed on or exempt from the Inventory.
Version: 1.1 Revision Date: 02/20/2019 16.Other information, including date of preparation or last revision Revision Date: 02/20/2019 Version #: 1.1 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
