SDS

ManualsBrandsSummit Brands ManualsBathroom CleanersSuper Iron Out 7.6 Oz. Automatic Toilet Bowl Cleaner (4-Pack)

SAFETY DATA SHEET

1. Product and Company Identification

Iron Out Automatic Toilet Bowl CleanerProduct identifier

Not available

Other means of identification

Not available.

Recommended use

None known.

Recommended restrictions

Iron Out dba Summit Brands

6714 Pointe Inverness Way

Suite 200

Fort Wayne, IN 46804-7935 US

Phone: 260-483-2519

Emergency Phone: 1-800-424-9300 (CHEMTREC)

Manufacturer information

See above.

Supplier

2. Hazards Identification

Not classified.

Physical hazards

Category 2Skin corrosion/irritation

Health hazards

Category 1Serious eye damage/eye irritation

Category 1BReproductive toxicity

Not classified.

Environmental hazards

Not classified

WHMIS 2015 defined hazards

Label elements

Signal word

Danger

Hazard statement

Causes skin irritation. Causes serious eye damage. May damage fertility or the unborn child.

Precautionary statement

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read

and understood. Wash thoroughly after handling. Wear protective gloves, protective clothing, eye

protection and face protection.

Response

IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off

contaminated clothing and wash it before reuse. Specific treatment (see information on this label).

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

IF exposed or concerned: Get medical attention.

Storage

Store locked up.

Disposal

Dispose of container in accordance with local, regional, national and international regulations.

None known

WHMIS 2015: Health Hazard(s)

not otherwise classified

(HHNOC)

None known

WHMIS 2015: Physical

Hazard(s) not otherwise

classified (PHNOC)

Hazard(s) not otherwise

classified (HNOC)

None known.

Supplemental information

None.

3. Composition/Information on Ingredients

Mixture

CAS number %Common name and synonymsChemical name

125-12-2

1-5*

Bicyclo[2.2.1]heptan-2-ol,

1,7,7-trimethyl-, acetate, exo-

142-78-9

10-30*

Dodecanamide, N-(2-hydroxyethyl)-

#15661 Issue date 03-December-2018

Page: 1 of 12

Summary of content (12 pages)

PAGE 1
SAFETY DATA SHEET 1. Product and Company Identification Product identifier Iron Out Automatic Toilet Bowl Cleaner Other means of identification Not available Recommended use Not available. Recommended restrictions None known. Manufacturer information Iron Out dba Summit Brands 6714 Pointe Inverness Way Suite 200 Fort Wayne, IN 46804-7935 US Phone: 260-483-2519 Emergency Phone: 1-800-424-9300 (CHEMTREC) See above. Supplier 2. Hazards Identification Physical hazards Not classified.
PAGE 2
Chemical name Common name and synonyms CAS number % Methanol 67-56-1 0.1-1* Monoethanolamine 141-43-5 1-5* N-(2-hydroxyethyl)myristamide 142-58-5 5-10* N-(2-hydroxyethyl)oleamide 111-58-0 1-5* Octadecanamide, N-(2-hydroxyethyl)- 111-57-9 1-5* Palmidrol 544-31-0 1-5* Sodium carboxymethyl cellulose 9004-32-4 1-5* Sodium hydrosulfite 7775-14-6 10-30* Sodium lauryl sulfate 151-21-3 5-10* All concentrations are in percent by weight unless ingredient is a gas.
PAGE 3
Methods and materials for containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
PAGE 4
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value Monoethanolamine (CAS 141-43-5) TWA 262 mg/m3 200 ppm STEL 15 mg/m3 6 ppm TWA 7.5 mg/m3 3 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Methanol (CAS 67-56-1) PEL 260 mg/m3 200 ppm Monoethanolamine (CAS 141-43-5) PEL 6 mg/m3 3 ppm US.
PAGE 5
Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.
PAGE 6
Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Chemical stability Material is stable under normal conditions. Conditions to avoid Do not mix with other chemicals. Incompatible materials Strong oxidizing agents. Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of sulfur. Hydrogen sulphide. 11. Toxicological Information Routes of exposure Eye, Skin contact, Inhalation, Ingestion.
PAGE 7
Components Species Test Results 87.5 mg/L, 6 Hours, ECHA 83.2 - 128.8 mg/l/4h, SIDS report/HSDB 82.1 mg/L, 6 Hours, ECHA Oral LD50 Dog 8000 mg/kg, HSDB Human 143 - 300 mg/kg, HSNO CCID/Sigma-Aldrich Monkey 7000 - 9000 mg/kg, ECHA 6000 mg/kg, ECHA 3000 mg/kg, RTECS 2000 mg/kg, HSDB Mouse 7300 mg/kg, HSDB Pig > 5000 mg/kg, ECHA Rabbit 14200 - 14400 mg/kg, RTECS 14.
PAGE 8
Components Species Test Results N-(2-hydroxyethyl)oleamide (CAS 111-58-0) Acute Dermal LD50 Not available Inhalation LC50 Not available Oral LD50 Not available Octadecanamide, N-(2-hydroxyethyl)- (CAS 111-57-9) Acute Dermal LD50 Rabbit > 2000 mg/kg, 24 Hours, ECHA Oral LD50 Rat > 3000 mg/kg, ECHA > 2000 mg/kg, ECHA Palmidrol (CAS 544-31-0) Acute Dermal LD50 Not available Inhalation LC50 Not available Oral LD50 Not available Sodium carboxymethyl cellulose (CAS 9004-32-4) Acute Dermal LD5
PAGE 9
Components Species Test Results 1427 mg/kg, ECHA 1288 mg/kg, HSDB 1200 mg/kg, ECHA 977 mg/kg, ECHA Causes skin irritation. Skin corrosion/irritation Exposure minutes Not available. Erythema value Not available. Oedema value Not available. Causes serious eye damage. Serious eye damage/eye irritation Corneal opacity value Not available. Iris lesion value Not available. Conjunctival reddening value Not available. Conjunctival oedema value Not available. Recover days Not available.
PAGE 10
Components Fish LC50 Sodium hydrosulfite (CAS 7775-14-6) Algae IC50 Crustacea EC50 Sodium lauryl sulfate (CAS 151-21-3) Algae IC50 Species Test Results Crucian carp (Carassius carassius) > 20000 mg/L, 96 hours Algae 120 mg/L, 72 Hours Daphnia 98 mg/L, 48 Hours Algae 53 mg/L, 72 Hours Crustacea EC50 Daphnia 1.8 mg/L, 48 Hours Aquatic Fish LC50 Carp, hawk fish (Cirrhinus mrigala) 1.
PAGE 11
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Methanol (CAS 67-56-1) Listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed.
PAGE 12
US. Rhode Island RTK Methanol (CAS 67-56-1) Monoethanolamine (CAS 141-43-5) Sodium hydrosulfite (CAS 7775-14-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.