MSDS

Document #: ALK NA PSDS Issue Date: 4/16/2010
Supersedes: GMEL 2002.9 – NA Reaffirmed: 01/01/2012
Updated: 2/27/2013
SECTION III - COMPOSITION AND INGREDIENTS
The chemicals and metals in this product are contained in a sealed can. Exposure to the contents will not
occur unless the battery leaks, is exposed to high temperatures or is mechanically, physically, or
electrically abused. Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS
under the HPA:
Chemical Name
CAS No.
Composition
Range
LD50/LC50
Exposure Limits
Manganese Dioxide
1313-13-9 35-40% LD50 oral
rat>3478 mg/kg
5 mg/m3 Ceiling OSHA PEL
0.2 mg/m3 TWA ACGIH TLV
Zinc
7440-66-6 10-25%
None established for zinc metal
Potassium Hydroxide
1310-58-3 5-10% LD50 oral rat
273 mg/kg
2 mg/m3 Ceiling ACGIH TLV
Graphite (natural or
synthetic)
7782-42-5;
7440-44-0
1-5%
Natural: 15 mppcf TWA OSHA PEL
2 mg/m3 TWA (respirable dust) ACGIH
TLV; Synthetic: 5 mg/m3 TWA (respirable
dust), 15 mg/m3 TWA (total dust) OSHA
PEL
2 mg/m3
SECTION IV – FIRST AID INFORMATION
Damaged battery will release concentrated potassium hydroxide, which is caustic.
Ingestion: Do not induce vomiting. Seek medical attention immediately. CALL NATIONAL
BATTERY INGESTION HOTLINE at (202)-625-3333 collect, day or night.
Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes. Seek medical
attention if irritation persists.
Skin Contact: Remove contaminated clothing and wash skin with soap and water. If irritation persists,
seek medical attention.
Inhalation: Move to fresh air. If irritation persists, seek medical attention.
SECTION V - FIRE FIGHTING INFORMATION
Hazardous Combustion Products: Thermal degradation may produce hazardous fumes of zinc and
manganese; hydrogen gas, caustic vapors of potassium hydroxide and other toxic by-products.
Extinguishing Media: Use any extinguishing media that is appropriate for the surrounding area.
Protection of Firefighters:
Specific Hazards Arising from the Material
: Batteries may burst and release hazardous decomposition
products when exposed to a fire situation.
Protective Equipment and Precautions for Firefighters: Firefighters should wear positive pressure self-
contained breathing apparatus and full protective clothing.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Notify safety personnel of large spills. Caustic potassium hydroxide may be released from leaking or
ruptured batteries. Clean-up personnel should wear appropriate clothing to avoid eye and skin contact
and inhalation of vapors and fumes. Ventilate area. Carefully collect batteries and place in an
appropriate container for disposal.
SECTION VII – HANDLING AND STORAGE