MSDS

ManualsBrandsQuikrete ManualsKitchen10.1 oz. Polyurethane Mortar Joint Sealant

Polyurethane Construction Adhesive

MATERIAL SAFETY DATA SHEET

(Complies with OSHA 29 CFR 1910.1200)

SECTION I: PRODUCT IDENTIFICATION

The QUIKRETE

Companies Emergency Telephone Number

One Securities Centre (770) 216-9580

3490 Piedmont Road, Suite 1300

Atlanta, GA 30329 Information Telephone Number

(770) 216-9580

MSDS X3

Revision: Apr-12

QUIKRETE

Product Name Code #

POLYURETHANE CONSTRUCTION ADHESIVE 9902-10

POLYURETHANE MORTAR JOINT SEALANT 8620-18

POLYURETHANE CONCRETE CRACK SEALANT 8620-17

FASTSET CONCRETE CRACK SEALANT 8620-26

PRODUCT USE: POLYURETHANE BASED SEALANTS FOR USE IN GENERAL CONSTRUCTION

SECTION II – HAZARDS IDENTIFICATION

Please note that as a service to our customers, hazard warnings and information have been

included for ALL chemicals listed in this MSDS. However, not all of these chemicals are

defined as “hazardous” by ISO or OSHA standards. Only those chemicals listed in Section 2 of

this MSDS are defined by ISO and/or OSHA as “hazardous” based upon the properties and

concentrations of each chemical.

MOST IMPORTANT HAZARDS

EYE: Direct contact irritates moderately with redness and swelling. Calcium carbonate,

xylene, calcium oxide, and MDI may cause severe eye irritation, especially in dust

form. Butyl benzyl phthalate (BBP) may cause irritation with symptoms of redness

and itching.

SKIN: A single short exposure (less than 24 hours) may irritate. Repeated prolonged

contact (24 to 48 hours) may irritate moderately. Product contains calcium

carbonate, xylene, and calcium oxide, which are possible skin sensitizers.

Contact with BBP may cause irritation with symptoms of redness and itching. MDI

may cause irritation to the skin or mucous membranes. Ethyl benzene may be

absorbed through the skin.

Summary of content (16 pages)

PAGE 1
Polyurethane Construction Adhesive MATERIAL SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.
PAGE 2
INHALATION: Vapor overexposure, and/or inhalation of silica or calcium oxide dust may severely irritate eyes, nose, throat, upper respiratory tract, and lungs. Vapor overexposure may cause drowsiness. Excessive inhalation of calcium carbonate (dust form) may result in shortness of breath or reduced pulmonary function.
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CAS NO. INGREDIENT WT LETHAL DOSES % EXPOSURE LIMITS ppm 1330-20- Xylene 7 1-5 101-68-8 Diphenylmethane diisocyanate (MDI) Inhalation LC50 – 5,000 ppm/4hr (rat) Oral LD50 – 4,300 mg/kg (rat) Dermal LD50 – >1,700 mg/kg (rabbit) 0.5- Inhalation LC50 – 1.
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SKIN CONTACT: EYE CONTACT: INGESTION: COMMENTS: Remove from skin and wash thoroughly with soap and water or waterless cleanser. Get medical attention if irritation or other ill effects develop or persist. Immediately flush with water for 15 minutes. Get medical attention. Get medical attention. Treat according to person’s condition and specifics of exposure. SECTION V – FIRE-FIGHTING MEASURES SUITABLE EXTINGUISHING MEDIA: Carbon Dioxide (CO2), water fog dry chemical, foam.
PAGE 5
SECTION VII – HANDLING AND STORAGE HANDLING: STORAGE: Assure good ventilation Eliminate sources of ignition. Store in original sealed containers away from heat and moisture. Shelf-life 12 months at 73°F and 50% relative humidity. SECTION VIII – EXPOSURE CONTROL AND PERSONAL PROTECTION ENGINEERING CONTROLS: LOCAL EXHAUST: GENERAL VENTILATION: Recommended Recommended PERSONAL PROTECTIVE EQUIPMENT: EYE PROTECTION: Avoid eye contact. Use proper protection - safety glasses as a minimum.
PAGE 6
VAPOR PRESSURE (AT 100°F): Not Applicable VAPOR DENSITY: 3.66 (Xylene) DENSITY: 10.7 lb/gal SOLUBILITY IN WATER (%): NIL SPECIFIC GRAVITY (AT 77°F/25°C): 1.28 VISCOSITY (AT 77°F/25°C): Greater than 700,000 cps (@ 2 rpm) FREEZING / MELTING POINT: Not Applicable ODOR THRESHOLD: Not Determined EVAPORATION RATE: Not Applicable % VOLATILE BY VOLUME: Less than 6% VOLATILE ORGANIC CONTENT (VOC): 3.53% by weight; 45 g/L (0.
PAGE 7
Dermal LD50 – 6,700 mg/kg (rat) FOR CALCIUM CARBONATE: Oral LD50 – 7,340 mg/kg (rat) FOR CALCIUM OXIDE: Not established.
PAGE 8
ORAL: Small amounts transferred to the mouth by fingers during use, etc. should not injure. Swallowing larger quantities may have adverse effects depending on quantity ingested. Repeated ingestion of BBP may cause sleepiness, withdrawal, and weight loss or decreased weight gain. Ingestion of xylene may cause central nervous system effects. SPECIFIC EFFECTS: This material contains the following components with the special hazards listed below. Carcinogens: See below.
PAGE 9
EC50 (Green algae): 1.5 mg/L (72hr) FOR CALCIUM CARBONATE: Environmental Fate: This chemical is not expected to have a significant impact when released into the environment. Environmental Toxicity: TLm (Mosquito Fish): 240 ppm/24hr; 220 ppm/48hr; 160 ppm/96hr at 70-73.5 degrees F (21-23 degrees C) FOR CALCIUM OXIDE: Environmental Fate: Environmental Toxicity: FOR TITANIUM DIOXIDE: Environmental Fate: Environmental Toxicity: Not available. This chemical is expected to be toxic to aquatic life.
PAGE 10
FOR ETHYL BENZENE: Environmental Fate: No information available. Environmental Toxicity: This chemical is expected to be toxic to aquatic life. Fish: Rainbow Trout: LC50 – 14.0 mg/L/96hr Static Bioassay Fish: Fathead Minnow: LC50 – 12.1 mg/L/96hr Flow-through Bioassay Fish: Bluegill/Sunfish: LC50 – 150.0 mg/L/96hr Static Bioassay, pH 6.5-7.9, 21-23 degrees C, Water flea: EC50 – 2.1 mg/L/48hr Static Bioassay Water Flea: EC50 – 75.0 mg/L/48hr Static Bioassay Shrimp (mysidoposis bahia): LC50 – 87.
PAGE 11
US FEDERAL REGULATIONS: Occupational Health and Safety Administration (OSHA) Ingredients listed on National Toxicology Program (NTP) Annual Report on Carcinogens The following ingredients are known to be human carcinogens. ♦ Silica, quartz (Silica, crystalline) 14808-60-7 ♦ Vinyl chloride 75-01-4 The following ingredients are reasonably anticipated to be human carcinogens.
PAGE 12
These sections require emergency planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable Quantities (RQs) of “Extremely Hazardous Substances” (EHS) listed in Appendix A of 40 CFR 355. Chemical Furan Propylene oxide - CAS No. 110-00-9 75-56-9 Wt% < 0.0006 < 0.0002 RQ (lbs) 100 100 TPQ (lbs) 500 10,000 Section 311/312 These sections require Tier I/Tier II - Emergency and hazardous chemical inventory form.
PAGE 13
Vinyl chloride Furan Propylene oxide Acetaldehyde 75-01-4 110-00-9 75-56-9 75-07-0 < 0.002 < 0.0006 < 0.0002 < 0.00005 1 100 100 1,000 US STATE REGULATIONS: California California Safe Drinking Water and Toxic Enforcement Act – Proposition 65 This product contains the following chemical currently listed under California Proposition 65. Chemical CAS No.
PAGE 14
Xylene MDI Ethyl benzene Silica, quartz Toluenesulfonyl chloride Chlorobenzene Stannous 2-ethylhexanoate Vinyl chloride Furan Propylene oxide Acetaldehyde 1330-20-7 1-5 Delaware, Florida, Massachusetts, Michigan, Minnesota, New Jersey, New York, Pennsylvania, Washington 101-68-8 0.5-1.5 Delaware, Florida, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Washington 100-41-4 0.1-1.0 Delaware, Florida, Massachusetts, Minnesota, New Jersey, New York, Pennsylvania, Washington 14808-60-7 < 0.
PAGE 15
Note: The recipient of this product should be aware of the possible existence of additional local regulations, which may be applicable to this product.
PAGE 16
respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products.