SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Print Date: 01/13/2016 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer 53862-89-8 >= 30.0 - <= 60.0 % Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 57029-46-6 >= 10.0 - <= 30.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 >= 10.0 - <= 30.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: If swallowed, seek medical attention.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 sources. Move container from fire area if this is possible without hazard. Use water spray to cool fireexposed containers and fire-affected zone until fire is out. Special protective equipment for firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves).
Issue Date: 01/04/2016 Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Storage stability Storage temperature: 49 °C (120 °F) Shelf life: Use within 12 Month 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Atmospheric levels should be maintained below the exposure guideline.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: No data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Possibility of hazardous reactions: Can occur.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Acute inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Mutagenicity In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other in vitro studies were negative. Animal mutagenicity studies were predominantly negative. Aspiration Hazard Based on physical properties, not likely to be an aspiration hazard.
Issue Date: 01/04/2016 Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Ecotoxicological information appears in this section when such data is available. Toxicity Polymethylenepolyphenyl polyisocyanate, polypropyleneglycol copolymer Acute toxicity to fish Not expected to be acutely toxic to aquatic organisms.
Issue Date: 01/04/2016 Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or Equivalent Acute toxicity to aquatic invertebrates Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline 202 or Equivalent Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Acute toxicity to algae/aquatic plants ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test Chronic toxicity to aquatic invertebrates NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of off
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Methyl ether Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301A or Equivalent Theoretical Oxygen Demand: 2.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer Bioaccumulation: No relevant data found. Diphenylmethane Diisocyanate, isomers and homologues Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with water.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Methyl ether Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 1.29 - 14 Estimated. Propane Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient(Koc): 24 - 460 Estimated. Tris(1-chloro-2-propyl) phosphate Potential for mobility in soil is slight (Koc between 2000 and 5000).
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 Packing group This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations.
Product name: GREAT STUFF™ Window and Door Insulating Foam Sealant STW 16oz HC ES 24ct Issue Date: 01/04/2016 16. OTHER INFORMATION Revision Identification Number: 101187825 / A001 / Issue Date: 01/04/2016 / Version: 7.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH Asphyxiant C NIOSH REL OSHA Z-1 STEL TWA US WEEL USA. ACGIH Threshold Limit Values (TLV) Asphyxiant Ceiling USA. NIOSH Recommended Exposure Limits USA.