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Cylindrical Lithium Manganese Dioxide Batteries

January 2013

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PRODUCT SAFETY DATA SHEET

PRODUCT NAME: Energizer Battery

Type No.:

Volts: 3.0

TRADE NAMES: Cylindrical Lithium Manganese Dioxide Batteries

Approximate Weight: 11 – 40 g.

CHEMICAL SYSTEM: Lithium Manganese Dioxide

Designed for Recharge: No

SECTION 1- MANUFACTURER INFORMATION

Manufactured for

Energizer Battery Manufacturing, Inc.

Telephone Number for Information:

25225 Detroit Rd.

Westlake, OH 44145

800-383-7323 (USA / CANADA)

Date Prepared: January 2013

SECTION 2 – HAZARDS IDENTIFICATION

Under normal conditions of use, the battery is hermetically sealed.

Ingestion: Swallowing a battery can be harmful.

Inhalation: Contents of an open battery can cause respiratory irritation.

Skin Contact: Contents of an open battery can cause skin irritation.

Eye Contact: Contents of an open battery can cause severe irritation.

SECTION 3 - INGREDIENTS

IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be

harmful.

MATERIAL OR INGREDIENT

PEL (OSHA)

TLV (ACGIH)

%/wt.

Carbon Black

(CAS# 1333-86-4)

3.5 mg/m

TWA

3.5 mg/m

TWA

0-1

1,2-Dimethoxyethane

(CAS# 110-71-4)

None established

0-6

1,3-Dioxolane

(CAS# 646-06-0)

None established

0-8

Graphite

(CAS# 7782-42-5)

15 mg/m

TWA (total dust)

5 mg/m

TWA (respirable fraction)

2 mg/m

TWA (respirable fraction)

0-3

Lithium or Lithium Alloy

(CAS# 7439-93-2)

None established

1-6

Lithium Trifluoromethanesulfonate

(CAS# 33454-82-9)

None established

0-3

Lithium Trifluoromethanesulfonimide

(CAS# 90076-65-6)

None established

0-3

Manganese Dioxide

(CAS# 1313-13-9)

5 mg/m

Ceiling (as Mn)

0.2 mg/m

TWA (as Mn)

12-42

Propylene Carbonate

(CAS# 108-32-7)

None established

0-8

Summary of content (5 pages)

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Page 1 of 4 Cylindrical Lithium Manganese Dioxide Batteries January 2013 PRODUCT SAFETY DATA SHEET PRODUCT NAME: Energizer Battery Type No.: TRADE NAMES: Cylindrical Lithium Manganese Dioxide Batteries CHEMICAL SYSTEM: Lithium Manganese Dioxide Volts: 3.0 Approximate Weight: 11 – 40 g. Designed for Recharge: No SECTION 1- MANUFACTURER INFORMATION Manufactured for Energizer Battery Manufacturing, Inc. 25225 Detroit Rd.
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Page 2 of 4 Cylindrical Lithium Manganese Dioxide Batteries January 2013 Non-Hazardous Components: Steel (iron CAS# 7439-89-6) Plastic and Other None established None established 20 None established None established Balance SECTION 4 – FIRST AID MEASURES Ingestion: Do not induce vomiting or give food or drink. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water.
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Page 3 of 4 Cylindrical Lithium Manganese Dioxide Batteries January 2013 Labeling: If the Energizer label or package warnings are not visible, it is important to provide a package and/or device label stating: WARNING: Battery can explode or leak and cause burns if installed backwards, disassembled, charged, or exposed to water, fire or high temperature. Where accidental ingestion of small batteries is possible, the label should include: (1) KEEP OUT OF REACH OF CHILDREN.
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Page 4 of 4 Cylindrical Lithium Manganese Dioxide Batteries January 2013 SECTION 10 – STABILITY AND REACTIVITY Lithium manganese dioxide batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity. SECTION 11 – TOXICOLOGICAL INFORMATION Lithium manganese dioxide batteries are not hazardous waste. Under normal conditions of use, lithium manganese dioxide batteries are non-toxic.
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Page 5 of 4 Cylindrical Lithium Manganese Dioxide Batteries January 2013 Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section 1910.1200 (c), Eveready/Energizer batteries are manufactured articles, which do not result in exposure to a hazardous chemical under normal conditions of use.