Version: 1.0 Revision Date: 03/28/2016 SAFETY DATA SHEET 1. Identification Material name: VULKEM 116 LV BLACK 30 CTG/CS Material: 426802L 323 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2.
Version: 1.0 Revision Date: 03/28/2016 Signal Word: Danger Hazard Statement: Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Toxic to aquatic life. Precautionary Statement: Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. [In case of inadequate ventilation] wear respiratory protection.
Version: 1.0 Revision Date: 03/28/2016 Carbon Black 1333-86-4 0.1 - 1% 1,3,5-Trimethylbenzene 108-67-8 0.1 - 1% Polymethylene polyphenyl isocyanate 9016-87-9 0.1 - 1% Crystalline Silica (Quartz)/ Silica Sand 14808-60-7 0.1 - 1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Trade secret information: ** A specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4.
Version: 1.0 Revision Date: 03/28/2016 Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Ventilate closed spaces before entering them. Evacuate area. See Section 8 of the SDS for Personal Protective Equipment. Keep upwind. Keep unauthorized personnel away.
Version: 1.0 Revision Date: 03/28/2016 PEL 15 mg/m3 TWA 15 mg/m3 TWA 50 millions of particles per cubic foot of air 5 mg/m3 TWA 15 millions of particles per cubic foot of air 200 mg/m3 TWA Heavy aromatic naphtha - Non-aerosol. - as total hydrocarbon vapor Heavy aromatic naphtha TWA PEL 100 ppm 1,2,4-Trimethylbenzene TWA 25 ppm 4,4'-Methylene bis(phenylisocyanate) TWA 0.005 ppm Ceiling 0.02 ppm 0.2 mg/m3 Carbon Black Inhalable fraction.
Version: 1.0 Revision Date: 03/28/2016 Chemical name type Exposure Limit Values Diisodecyl phthalate TWAEV Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 TWA 10 mg/m3 5 mg/m3 Source Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Canada. British Columbia OELs.
Version: 1.0 Revision Date: 03/28/2016 Calcium Carbonate (Limestone) Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyethylene Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Polyethylene Respirable particles. TWAEV 3 mg/m3 Polyethylene Inhalable TWAEV 10 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Heavy aromatic naphtha - Non-aerosol.
Version: 1.0 Revision Date: 03/28/2016 bis(phenylisocyanate) 4,4'-Methylene bis(phenylisocyanate) TWA 0.005 ppm TWAEV 0.005 ppm CEV 0.02 ppm 4,4'-Methylene bis(phenylisocyanate) TWA 0.005 ppm Carbon Black Inhalable TWA Carbon Black TWAEV 3.5 mg/m3 Carbon Black TWA 3.5 mg/m3 1,3,5-Trimethylbenzene TWA 25 ppm 1,3,5-Trimethylbenzene TWAEV 25 ppm 1,3,5-Trimethylbenzene TWA 25 ppm Polymethylene polyphenyl isocyanate TWA 0.005 ppm CEILING TWA 0.051 mg/m3 3 mg/m3 0.01 ppm 0.
Version: 1.0 Revision Date: 03/28/2016 Polymethylene polyphenyl isocyanate CEILING 0.01 ppm TWAEV 0.005 ppm CEV 0.02 ppm Polymethylene polyphenyl isocyanate TWA 0.005 ppm Crystalline Silica (Quartz)/ Silica Sand Respirable fraction. TWA 0.025 mg/m3 Crystalline Silica (Quartz)/ Silica Sand Respirable. Crystalline Silica (Quartz)/ Silica Sand Respirable dust. TWAEV 0.10 mg/m3 Appropriate Engineering Controls TWA 0.051 mg/m3 0.
Version: 1.0 Revision Date: 03/28/2016 Hygiene measures: Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. Contaminated work clothing should not be allowed out of the workplace. Avoid contact with skin. 9. Physical and chemical properties Appearance Physical state: solid Form: Paste Color: Black Odor: Mild Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available.
Version: 1.0 Revision Date: 03/28/2016 Hazardous Decomposition Products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Causes mild skin irritation.
Version: 1.0 Revision Date: 03/28/2016 4,4'-Methylene bis(phenylisocyanate) in vivo (Rabbit): Read-across based on grouping of substances (category approach), Key study Carbon Black in vivo (Rabbit): Experimental result, Key study 1,3,5-Trimethylbenzene in vivo (Rabbit): Experimental result, Key study Serious Eye Damage/Eye Irritation Product: No data available.
Version: 1.0 Revision Date: 03/28/2016 Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity - Single Exposure Product: No data available. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Aspiration Hazard Product: Other effects: No data available. No data available. 12.
Version: 1.0 Revision Date: 03/28/2016 Specified substance(s): Heavy aromatic naphtha NOAEL (Oncorhynchus mykiss, 28 d): 0.098 mg/l QSAR QSAR, Key study Aromatic petroleum distillates LL 50 (Pimephales promelas, 14 d): 5.2 mg/l Experimental result, Supporting study EC 50 (Daphnia magna, 21 d): 10 mg/l Other, Key study NOAEL (Pimephales promelas, 14 d): 2.6 mg/l Experimental result, Supporting study NOAEL (Daphnia magna, 21 d): 2.6 mg/l Other, Key study Carbon Black NOAEL (Salmo sp.
Version: 1.0 Revision Date: 03/28/2016 Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Chemical Identity P-chlorobenzotrifluoride Reportable quantity De minimis concentration: 1.0% One-Time Export Notification only. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) None present or none present in regulated quantities. CERCLA Hazardous Substance List (40 CFR 302.
Version: 1.0 Revision Date: 03/28/2016 SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Diisodecyl phthalate 4,4'-Methylene 5000 lbs. bis(phenylisocyanate) Polymethylene 5000 lbs. polyphenyl isocyanate Cumene 5000 lbs. 2,4-Toluene diisocyanate 100 lbs. Xylene 100 lbs. Toluene-2,6-Diisocyanate 100 lbs. Ethylbenzene 1000 lbs.
Version: 1.0 Revision Date: 03/28/2016 US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate (Limestone) P-chlorobenzotrifluoride Heavy aromatic naphtha 1,2,4-Trimethylbenzene Carbon Black Crystalline Silica (Quartz)/ Silica Sand US. Massachusetts RTK - Substance List Chemical Identity Calcium Carbonate (Limestone) Heavy aromatic naphtha 1,2,4-Trimethylbenzene Crystalline Silica (Quartz)/ Silica Sand 2,4-Toluene diisocyanate Toluene-2,6-Diisocyanate US.
Version: 1.0 Revision Date: 03/28/2016 Korea Existing Chemicals Inv. (KECI): One or more components in this product are not listed on or exempt from the Inventory. Canada NDSL Inventory: One or more components in this product are not listed on or exempt from the Inventory. Philippines PICCS: One or more components in this product are not listed on or exempt from the Inventory. US TSCA Inventory: All components in this product are listed on or exempt from the Inventory.