Version: 1.1 Revision Date: 02/05/2019 1. Identification SAFETY DATA SHEET Material name: VULKEM 116 LV BLACK 12 CTG/CS Material: 426802M 312 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: Telephone: Emergency telephone number: EH&S Department 216-292-5000 1-800-424-9300 (US); 1-613-996-6666 (Canada) 2.
Version: 1.1 Revision Date: 02/05/2019 Label Elements Hazard Symbol: Signal Word: Danger Hazard Statement: Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause genetic defects. May cause cancer. Toxic to aquatic life. Precautionary Statements Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. [In case of inadequate ventilation] wear respiratory protection.
Version: 1.1 Revision Date: 02/05/2019 Calcium Carbonate (Limestone) Polyethylene Heavy aromatic naphtha Aromatic petroleum distillates 1,2,4-Trimethylbenzene 4,4'-Methylene bis(phenylisocyanate) Carbon Black 1,3,5-Trimethylbenzene Polymethylene polyphenyl isocyanate Crystalline Silica (Quartz)/ Silica Sand 1317-65-3 10 - 30% 9002-88-4 3 - 7% 64742-94-5 64742-95-6 95-63-6 101-68-8 1333-86-4 108-67-8 9016-87-9 14808-60-7 1 - 5% 1 - 5% 1 - 5% 0.5 - 1.5% 0.1 - 1% 0.1 - 1% 0.1 - 1% 0.
Version: 1.1 Revision Date: 02/05/2019 Specific hazards arising from the chemical: During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Special fire fighting procedures: No data available. Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6.
Version: 1.1 Revision Date: 02/05/2019 particles. Polyethylene - Respirable particles. Polyethylene - Respirable fraction. Polyethylene - Total dust. TWA 3 mg/m3 US. ACGIH Threshold Limit Values (03 2015) PEL 5 mg/m3 PEL 15 mg/m3 TWA 15 mg/m3 TWA 50 millions of particles per cubic foot of air 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) US. OSHA Table Z-3 (29 CFR 1910.
Version: 1.1 Revision Date: 02/05/2019 Chemical name Type Diisodecyl phthalate TWA 5 mg/m3 Calcium Carbonate (Limestone) - Total dust. STEL 20 mg/m3 TWA 10 mg/m3 Calcium Carbonate (Limestone) - Respirable fraction. TWA 3 mg/m3 Calcium Carbonate (Limestone) - Total dust. TWA 10 mg/m3 Polyethylene - Respirable fraction. TWA 3 mg/m3 Polyethylene - Total dust. TWA 10 mg/m3 Polyethylene - Inhalable fraction. Polyethylene - Respirable fraction. Polyethylene - Total dust.
Version: 1.1 Revision Date: 02/05/2019 4,4'-Methylene bis(phenylisocyanate) TWA 0.005 ppm CEV 0.02 ppm 4,4'-Methylene bis(phenylisocyanate) TWA 0.005 ppm 0.051 mg/m3 Carbon Black - Inhalable TWA 3 mg/m3 Carbon Black - Inhalable fraction. Carbon Black TWA 3 mg/m3 TWA 3.5 mg/m3 1,3,5-Trimethylbenzene TWA 25 ppm 1,3,5-Trimethylbenzene TWA 25 ppm 1,3,5-Trimethylbenzene TWA 25 ppm Polymethylene polyphenyl isocyanate TWA 0.005 ppm CEILING 123 mg/m3 0.
Version: 1.1 Revision Date: 02/05/2019 Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister.
Version: 1.1 Revision Date: 02/05/2019 Chemical Stability: Material is stable under normal conditions. Possibility of hazardous reactions: No data available. Conditions to avoid: Avoid heat or contamination. Incompatible Materials: Alcohols. Amines. Strong acids. Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates). Strong bases. Water, moisture.
Version: 1.1 Revision Date: 02/05/2019 Skin Corrosion/Irritation Product: Specified substance(s): Heavy aromatic naphtha No data available.
Version: 1.1 Revision Date: 02/05/2019 IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Carbon Black Overall evaluation: Possibly carcinogenic to humans. Crystalline Silica (Quartz)/ Silica Sand Overall evaluation: Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand US. OSHA Specifically Regulated Substances (29 CFR 1910.
Version: 1.1 Revision Date: 02/05/2019 Fish Product: Specified substance(s): 1,2,4-Trimethylbenzene Aquatic Invertebrates Product: No data available. LC 50 (Fathead minnow (Pimephales promelas), 96 h): 7.19 - 8.28 mg/l Mortality No data available. Chronic hazards to the aquatic environment: Fish Product: Specified substance(s): Heavy aromatic naphtha No data available. NOAEL (Oncorhynchus mykiss, 28 d): 0.098 mg/l QSAR QSAR, Key study Aquatic Invertebrates Product: No data available.
Version: 1.1 Revision Date: 02/05/2019 Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt.
Version: 1.1 Revision Date: 02/05/2019 SARA 302 Extremely Hazardous Substance Reportable Chemical Identity quantity 2,4-Toluene diisocyanate 100 lbs. Toluene-2,6-Diisocyanate 100 lbs. Threshold Planning Quantity 500 lbs. 100 lbs. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Diisodecyl phthalate 4,4'-Methylene 5000 lbs. bis(phenylisocyanate) Polymethylene polyphenyl isocyanate Cumene 5000 lbs. 2,4-Toluene diisocyanate 100 lbs. Xylene 100 lbs.
Version: 1.1 Revision Date: 02/05/2019 WARNING Cancer and Reproductive Harm - www.P65Warnings.ca.gov US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate (Limestone) P-chlorobenzotrifluoride Heavy aromatic naphtha 1,2,4-Trimethylbenzene Carbon Black Crystalline Silica (Quartz)/ Silica Sand US.
Version: 1.1 Revision Date: 02/05/2019 Regulatory VOC (less water and exempt solvent) : 49 g/l VOC Method 310 : 2.87 % Inventory Status: Australia AICS: One or more components in this product are not listed on or exempt from the Inventory. Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory.
Version: 1.1 Revision Date: 02/05/2019 Version #: 1.1 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition.
