SDS

ManualsBrandsMendocino Forest Products ManualsGarden CenterTreated Tree Stake

MATERIAL SAFETY

DATA SHEET

Wolmanized® CA-C Treated Wood

REVISION DATE : 09/21/2009 Page 1 of 14

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:

FOR ALL MSDS QUESTIONS & REQUESTS, CALL:

PRODUCT NAME: Wolmanized® CA-C Treated Wood

1. PRODUCT AND COMPANY IDENTIFICATION

Manufactured By:

REVISION DATE:

09/21/2009

SUPERCEDES:

03/20/2009

MSDS Number:

000000004504

SYNONYMS:

None

CHEMICAL

FAMILY:

DESCRIPTION /

USE:

Treated Wood Products

FORMULA:

None established

2. HAZARDS IDENTIFICATION

OSHA Hazard

Classification:

Wood dust is classified as: carcinogenic, possible sensitizer,

mild skin irritant, possible respiratory irritant., WARNING! MAY

FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR

(DURING PROCESSING)

Routes of Entry:

Inhalation, skin, eyes, ingestion

Chemical Interactions:

No known or reported interactions.

Medical Conditions

Aggravated:

Inhalation of the dust from this material at

concentrations above the TLV can aggravate pre-

existing upper respiratory and lung diseases such as

bronchitis, emphysema and asthma., Skin diseases

including eczema and sensitization

Human Threshold Response Data

Odor Threshold

Not established for product.

Amine

2.6 ppm

Irritation Threshold

Not established for product.

Amine

> 5.0 ppm

Summary of content (14 pages)

PAGE 1
MATERIAL SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL MSDS QUESTIONS & REQUESTS, CALL: PRODUCT NAME: Wolmanized® CA-C Treated Wood 1. PRODUCT AND COMPANY IDENTIFICATION Manufactured By: REVISION DATE: SUPERCEDES: 09/21/2009 03/20/2009 MSDS Number: SYNONYMS: CHEMICAL FAMILY: DESCRIPTION / USE: FORMULA: 000000004504 None Treated Wood Products None established 2.
PAGE 2
MATERIAL SAFETY DATA SHEET Hazardous Materials Identification System / National Fire Protection Association Classifications Hazard Ratings : Health Flammability HMIS NFPA 2* 2 1 1 Physical / Instability 0 0 PPI / Special hazard. Immediate (Acute) Health Effects Inhalation Toxicity: Airborne treated or untreated wood dust may cause nose, throat or lung irritation. Skin Toxicity: Handling of wood may result in skin exposure to splinters.
PAGE 3
MATERIAL SAFETY DATA SHEET Chronic Target Organ Toxicity: Supplemental Health Hazard Information : Respiratory Tract, Skin, Eyes No additional health information available. 3. COMPOSITION / INFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS # % RANGE COPPER COMPOUNDS MIXTURE Ethanolamine 141-43-5 Wood Dust Not Assigned 88 - 99.5 Ammonia (Only applies if treatment facility adds ammonia locally. Check with treatment facility to determine applicability.
PAGE 4
MATERIAL SAFETY DATA SHEET 5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): Product is not known to be flammable, combustible, pyrophoric or explosive. Flammable Properties Flash Point: Autoignition Temperature: No data. No data. Fire / Explosion Hazards: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
PAGE 5
MATERIAL SAFETY DATA SHEET Additional Spill Information : Remove all sources of ignition. Utilize emergency response personal protection equipment prior to the start of any response. Evacuate all non-essential personnel. Dust Deposits should not be allowed to accumulate on surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
PAGE 6
MATERIAL SAFETY DATA SHEET 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: Whenever possible, sawing or machining treated or untreated wood should be performed outdoors or in well ventilated areas to avoid accumulations of airborne wood dust.Ventilation should be sufficient to maintain exposures below the recommended exposure limits.
PAGE 7
MATERIAL SAFETY DATA SHEET Ethanolamine 141-43-5 NIOSH-IDLH 30 ppm Wood Dust ZUS_OSHAZ3 15.0 mg/m3 PEL Total dust (as nuisance dust) Wood Dust ZUS_OSHAZ3 5.0 mg/m3 PEL Respirable fraction. (as nuisance dust) Wood Dust ZUS_ACGIH 0.5 mg/m3 TWA inhalable fraction (Western Red Cedar) Wood Dust ZUS_ACGIH 1.0 mg/m3 TWA inhalable fraction (All other species) Ammonia (Only applies if treatment facility adds ammonia locally. Check with treatment facility to determine applicability.
PAGE 8
MATERIAL SAFETY DATA SHEET Formaldehyde (by-product of the untreated plywood article) 50-00-0 ZUS_OSHAP2 Formaldehyde (by-product of the untreated plywood article) Formaldehyde (by-product of the untreated plywood article) Formaldehyde (by-product of the untreated plywood article) Formaldehyde (by-product of the untreated plywood article) Formaldehyde (by-product of the untreated plywood article) Formaldehyde (by-product of the untreated plywood article) 50-00-0 ZUS_OSHAP1 0.
PAGE 9
MATERIAL SAFETY DATA SHEET Products: Decomposition Temperature: generated by thermal decomposition or combustion. No data 11. TOXICOLOGICAL INFORMATION Component Animal Toxicology Oral LD50 value: Ethanolamine LD50 = 1,700 mg/kg rat LD50 Approximately 1,000 mg/kg Dermal LD50 value: Ethanolamine rabbit Inhalation LC50 value: Ethanolamine Ethanolamine LC50 1 h LC50 4 h > 4.
PAGE 10
MATERIAL SAFETY DATA SHEET Ethanolamine This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. Chemicals of similar structure have been shown not to cause cancer in laboratory animals. 12. ECOLOGICAL INFORMATION Overview: No data for product. Individual constituents are as follows: Ecological Toxicity Values for: Ethanolamine Rainbow trout (Oncorhynchus - (nominal, static). 96 h LC50 = 150 mg/l mykiss) Mosquito fish - (nominal, static).
PAGE 11
MATERIAL SAFETY DATA SHEET 14. TRANSPORT INFORMATION Land (US DOT): Water (IMDG): NOT REGULATED AS A DOT HAZARDOUS MATERIAL NOT REGULATED AS A HAZARDOUS MATERIAL, Air (IATA): Flash Point: No data. NOT REGULATED AS A HAZARDOUS MATERIAL, Emergency Response Guide Number: Not applicable 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA): This item is exempt from TSCA and FIFRA under the treated article exemption per 40 CFR 152.25(a).
PAGE 12
MATERIAL SAFETY DATA SHEET HON SOC None established Clean Air Act VOC Section 111: CAA 111 None established Clean Air Act Haz.
PAGE 13
MATERIAL SAFETY DATA SHEET 2007-03-01 ETHANOLAMINE MONOETHANOLAMINE ETHANOL, 2-AMINOSpecial Health Hazard - Corrosive New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 DIPROPYLENE GLYCOL METHYL ETHER PROPANOL, 1(or 2)-(2METHOXYMETHYLETHOXY)- (2-METHOXYMETHYLETHOXY) PROPANOL New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 FORMALDEHYDE METHYL ALDEHYDE FORMALIN Special Health Hazard - Carcinogen, Special Health Hazard Corrosive, Special Health Hazard - Flammable - F
PAGE 14
MATERIAL SAFETY DATA SHEET article) ZUSCA_P65 California Proposition 65. Safe drinking water and toxic enforcement act. No Significant Risk Levels 40 µg/day Formaldehyde (gas) Carcinogen California Proposition 65. Safe drinking water and toxic enforcement act. No Significant Risk Levels 40 micrograms per day Formaldehyde (gas) California Proposition 65. Safe drinking water and toxic enforcement act. Formaldehyde Carcinogen WHMIS Hazard Classification: None established 16.