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MATERIAL SAFETY

DATA SHEET

COOL POOL FLIP PLOP RPL CARTRIDGE

REVISION DATE : 06/03/2013 Page 1 of 12

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL:

FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®:

FOR ALL MSDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE

USA: 1-423-780-2970)

1-800-424-9300 (OUTSIDE

USA: 1-703-527-3887)

1-800-511-MSDS (OUTSIDE

USA: 1-423-780-2347)

PRODUCT NAME: COOL POOL FLIP PLOP RPL CARTRIDGE

EPA Registration Number: 53735-2

1. PRODUCT AND COMPANY IDENTIFICATION

Arch Chemicals, Inc.

501 Merritt 7 PO Box 5204

Norwalk, CT 06856-5204

REVISION DATE: 06/03/2013

SUPERCEDES: 09/27/2010

MSDS Number: 000000016082

SYNONYMS: Trichloroisocyanuric Acid, TCCA,

Trichlor

CHEMICAL FAMILY: Chloroisocyanurates

DESCRIPTION / USE Swimming pool water treatment

FORMULA: C3CL3N3O3

2. HAZARDS IDENTIFICATION

OSHA Hazard

Classification:

Corrosive to eyes and skin, Lung toxin, Toxic by ingestion, Toxic by

inhalation (dust)., Oxidizer

Routes of Entry: Inhalation, skin, eyes, ingestion

Chemical Interactions: No known or reported interactions.

Medical Conditions Aggravated: Asthma, respiratory and cardiovascular disease

Human Threshold Response Data

Odor Threshold

Not established for product.

Irritation Threshold

Not established for product.

Summary of content (22 pages)

PAGE 1
MATERIAL SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: COOL POOL FLIP PLOP RPL CARTRIDGE EPA Registration Number: 53735-2 1. PRODUCT AND COMPANY IDENTIFICATION Arch Chemicals, Inc.
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MATERIAL SAFETY DATA SHEET Hazardous Materials Identification System / National Fire Protection Association Classifications Hazard Ratings : Health Flammability Physical / Instability HMIS NFPA 3 2 0 0 2 2 PPI / Special hazard. NFPA Oxidizer Class: Meets the criteria of an NFPA Class 1 Oxidizer Immediate (Acute) Health Effects Inhalation Toxicity: This product in the form of solid tablets is not an inhalation hazard.
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MATERIAL SAFETY DATA SHEET Inhalation: Skin Contact: Ingestion: Sensitization: Chronic Target Organ Toxicity: Supplemental Health Hazard Information : There are no known or reported effects from chronic exposure except for effects similar to those experienced from acute exposure. Effects similar to those from acute exposure. In addition, chronic exposure to wet material may cause effects secondary to tissue destruction.
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MATERIAL SAFETY DATA SHEET Ingestion: Notes to Physician: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Probable mucosal damage may contraindicate the use of gastric lavage. 5.
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MATERIAL SAFETY DATA SHEET Water Release: Land Release: Additional Spill Information : This material is heavier than water. This material is soluble in water. Stop water flow or divert water flow around spill if possible and safe to do so. Begin monitoring for available chlorine and pH immediately. Do not contaminate spill material with any organic materials, ammonia, ammonium salts or urea. Clean up all spill material with clean, dry dedicated equipment and place in a clean dry container.
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MATERIAL SAFETY DATA SHEET Respiratory Protection : Respirator Type : Skin Protection : Eye Protection: Protective Clothing Type: General Protective Measures: Wear a NIOSH approved respirator if levels above the exposure limits are possible. A NIOSH approved full-face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit.
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MATERIAL SAFETY DATA SHEET 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Conditions to Avoid: Chemical Incompatibility: Hazardous Decomposition Products: Decomposition Temperature: May be unstable at temperatures above 225 Deg. C (437 Deg. F) Not sensitive to mechanical shock. Not sensitive to static discharge. Product will not undergo hazardous polymerization. Product is an oxidizer. Sparks, open flame, other ignition sources, and elevated temperatures.
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MATERIAL SAFETY DATA SHEET Dermal LD50 value: Inhalation LC50 value: LD50 > 2,000 mg/kg Rabbit LC50 4 h (aerosol dust), (Nose Only) Approximately 0.54 MG/L (aerosol dust), (Nose Only) Approximately 2.16 MG/L Rat Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Corrosive to eyes.
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MATERIAL SAFETY DATA SHEET Ecological Toxicity Values for: TRICHLORO-S-TRIAZINETRIONE Rainbow trout (Salmo gairdneri), - 96 h LC50 0.32 mg/l Bluegill sunfish - 96 h LC50 0.30 mg/l Daphnia magna, - 48 h LC50 0.21 mg/l Mallard duck - 8 DAYS Dietary LC50 > 10,000 ppm Mallard duck Acute Oral LD50 1,600 mg/kg Bobwhite quail - 8 DAYS Dietary LC50 7,422 ppm 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL.
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MATERIAL SAFETY DATA SHEET Transportation Notes: Material is not regulated as a marine pollutant for ground transportation within the US if shipped in non-bulk packages. EMS: F-A, S-Q 15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA): EPA Pesticide Registration Number: FIFRA Listing of Pesticide Chemicals (40 CFR 180): This is an EPA registered pesticide. 53735-2 This product is regulated under the Federal Insecticide, Fungicide and Rodenticide Act.
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MATERIAL SAFETY DATA SHEET Clean Air Act Haz.
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MATERIAL SAFETY DATA SHEET WHMIS Hazard Classification: : : : : : Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 148 Trichloroisocyanuric acid Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 67 Boric acid 16. OTHER INFORMATION MSDS REVISION STATUS : SECTIONS REVISED: Major References : 11 Available upon request.
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Evaluation Warning : The document was created with Spire.PDF for .NET. MATERIAL SAFETY DATA SHEET FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL MSDS QUESTIONS & REQUESTS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME: COOL POOL FLIP PLOP SYSTEM - COOL POOL FLIP FLOP SYSTEM EPA Registration Number: 53735-11 1.
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MATERIAL SAFETY DATA SHEET Hazardous Materials Identification System / National Fire Protection Association Classifications Hazard Ratings : Health Flammability Physical / Instability HMIS NFPA 1 1 0 0 0 0 PPI / Special hazard. Immediate (Acute) Health Effects Inhalation Toxicity: Not expected to be irritating. Not expected to be toxic by inhalation. Skin Toxicity: Not expected to be irritating to the skin. Not expected to be absorbed through the skin. Not expected to be toxic from dermal contact.
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MATERIAL SAFETY DATA SHEET Silver Chloride 7783-90-6 < 1.0 4. FIRST AID MEASURES Inhalation: Skin Contact: Eye Contact: Ingestion: IF INHALED: Remove individual to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops. IF ON SKIN: Flush skin with water for 15 minutes. Take off all contaminated clothing. Seek medical attention if irritation develops. IF IN EYES: Flush eyes with plenty of water for at least 15 minutes.
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MATERIAL SAFETY DATA SHEET Additional Spill Information : Stop source of spill as soon as possible and notify appropriate personnel. Utilize emergency response personal protection equipment prior to the start of any response. Evacuate all nonessential personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. 7. HANDLING AND STORAGE Handling: Storage: Incompatible Materials for Storage: Do not take internally. Avoid contact with skin, eyes and clothing.
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MATERIAL SAFETY DATA SHEET Silver Chloride 7783-90-6 ACGIH 0.01 mg/m3 Calculated as Ag TWA soluble 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Form Color: Odor: Molecular Weight: Specific Gravity : pH : Boiling Point: Freezing Point: Melting Point: Density: Vapor Pressure: Vapor Density: Viscosity: Fat Solubility: Solubility in Water: Partition coefficient noctanol/water: Evaporation Rate: Oxidizing: Volatiles, % by vol.
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MATERIAL SAFETY DATA SHEET Silver Chloride Silver Chloride LD50 LD50 = 10,000 mg/kg mouse = 5,000 mg/kg guinea pig Component Animal Toxicology Dermal LD50 value: Silver Chloride no data available Product Animal Toxicity Oral LD50 value: Dermal LD50 value: Inhalation LC50 value: Skin Irritation: Eye Irritation: Skin Sensitization: Acute Toxicity: Subchronic / Chronic Toxicity: LD50 > 5,000 mg/kg LD50 > 5,000 mg/kg No data Rat Rabbit Not expected to be irritating.
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MATERIAL SAFETY DATA SHEET Pimephales promelas (fathead minnow) Cyprinodon variegatus (sheepshead minnow) Inland silverside Daphnia magna (Water flea) - 96 h LC50 = 0.510 mg/l - 96 h LC50 = 1.065 mg/l - 96 h LC50 = 0.26 mg/l 96 h LC50> 1.93 mg/l 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL.
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MATERIAL SAFETY DATA SHEET consistent with its labeling. Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311 / 312 (40 CFR 370.2): Health Physical None None Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity: ZUS_SAR302 TPQ (threshold planning None established quantity) Reportable Quantity (49 CFR 172.
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MATERIAL SAFETY DATA SHEET CAS # ZUSPA_RTK COMPONENT NAME None established New Jersey: CAS # 7783-90-6 ZUSNJ_RTK COMPONENT NAME Silver Chloride New Jersey Right to Know Hazardous Substance List (RTK-HSL) 2007-03-01 SILVER COMPOUNDS Massachusetts: CAS # ZUSMA_RTK California Proposition 65: CAS # ZUSCA_P65 COMPONENT NAME None established COMPONENT NAME None established WHMIS Hazard Classification: None established 16.
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MATERIAL SAFETY DATA SHEET COOL POOL FLIP PLOP SYSTEM - COOL POOL FLIP FLOP SYSTEM REVISION DATE : 06/04/2013 Page 10 of 10