SDS

ManualsBrandsGREAT STUFF ManualsBuilding materials16 oz. Big Gap Filler Insulating Foam Sealant

Product Name:

GREAT STUFF(TM) Big Gap Filler Insulating Foam

Sealant 16oz HC

Issue Date:

12/10/2012

Print Date:

14 Mar 2013

®(TM)*Trademark

Page

1 of 14

The Dow Chemical Company

encourages and expects you to read and understand the entire (M)SDS,

as there is important information throughout the document. We expect you to follow the precautions

identified in this document unless your use conditions would necessitate other appropriate methods or

actions.

1. Product and Company Identification

Product Name

GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC

COMPANY IDENTIFICATION

The Dow Chemical Company

2030 Willard H. Dow Center

Midland, MI 48674

United States

Customer Information Number: 800-258-2436

SDSQuestion@dow.com

EMERGENCY TELEPHONE

NUMBER

Hour Emergency Contact:

989-636-4400

Local Emergency Contact:

989-636-4400

2. Hazards Identification

Emergency Overview

Color: Yellow

Physical State: Foam

Odor: Mild

Hazards of product:

DANGER! Flammable gas - May cause flash fire. May cause allergic skin reaction.

May cause allergic respiratory reaction. May cause eye irritation. May cause skin

irritation. Vapor reduces oxygen available for breathing. May cause anesthetic

effects. May cause respiratory tract irritation. Vapors may travel a long distance;

ignition and/or flash back may occur. Evacuate area. Keep upwind of spill. Stay out

of low areas. Aerosol cans exposed to fire can rupture becoming flaming projectiles.

Elevated temperatures can cause hazardous polymerization. Toxic fumes may be

released in fire situations. Contents under pressure. Avoid temperatures above 49°C

(120.2°F)

OSHA Hazard Communication Standard

Material Safety Data Sheet

The Dow Chemical Company

Summary of content (14 pages)

PAGE 1
Material Safety Data Sheet The Dow Chemical Company Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Print Date: 14 Mar 2013 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
PAGE 2
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Potential Health Effects Eye Contact: May cause eye irritation. May cause slight temporary corneal injury. Skin Contact: Prolonged contact may cause moderate skin irritation with local redness. Material may stick to skin causing irritation upon removal. May stain skin.
PAGE 3
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air.
PAGE 4
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Unusual Fire and Explosion Hazards: Contains flammable propellant. Aerosol cans exposed to fire can rupture and become flaming projectiles. Propellant release may result in a fireball. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns.
PAGE 5
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Storage Minimize sources of ignition, such as static build-up, heat, spark or flame. Store in a dry place. See Section 10 for more specific information. Shelf life: Use within Do not store above: 12 Months 49 °C 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value ACGIH TWA 0.005 ppm OSHA Table Z-1 Ceiling 0.2 mg/m3 0.
PAGE 6
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC 9.
PAGE 7
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Decomposition products depend upon temperature, air supply and the presence of other materials. Toxic gases are released during decomposition. 11. Toxicological Information Acute Toxicity Ingestion As product: Single dose oral LD50 has not been determined. Estimated. LD50, rat > 2,000 mg/kg Dermal As product: The dermal LD50 has not been determined. Estimated.
PAGE 8
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Fish Acute & Prolonged Toxicity Based on information for a similar material: LC50, Danio rerio (zebra fish), static test, 96 h: > 1,000 mg/l Aquatic Invertebrate Acute Toxicity Based on information for a similar material: EC50, Daphnia magna (Water flea), static test, 24 h: > 1,000 mg/l Aquatic Plant Toxicity Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static te
PAGE 9
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Toxicity to Micro-organisms EC50, OECD 209 Test; activated sludge, Respiration inhibition, 3 h: 784 mg/l Aquatic Invertebrates Chronic Toxicity Value Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, NOEC: 32 mg/l Data for Component: Isobutane No relevant data found. Data for Component: Propane No relevant data found.
PAGE 10
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Theoretical Oxygen Demand: 1.17 mg/mg Data for Component: Isobutane Biodegradation may occur under aerobic conditions (in the presence of oxygen). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.44E-12 cm3/s 4.4 d Estimated. Theoretical Oxygen Demand: 3.58 mg/mg Data for Component: Propane No relevant data found.
PAGE 11
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 Mobility in soil Data for Component: Diphenylmethane Diisocyanate, isomers and homologues Mobility in soil: In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas.
PAGE 12
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC 14. Issue Date: 12/10/2012 Transport Information DOT Non-Bulk NOT REGULATED CONSUMER COMMODITY RECLASSIFIED AS ORM-D MATERIAL DOT Bulk NOT REGULATED IMDG Proper Shipping Name: AEROSOLS Hazard Class: 2.1 ID Number: UN1950 EMS Number: F-D,S-U LIMITED QUANTITY ICAO/IATA Proper Shipping Name: AEROSOLS Hazard Class: 2.
PAGE 13
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC Issue Date: 12/10/2012 The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting. Component CAS # Amount Diphenylmethane Diisocyanate, isomers and 9016-87-9 >= 10.0 - <= 30.0 % homologues 4,4' -Methylenediphenyl diisocyanate 101-68-8 >= 5.0 - <= 10.0 % Methyl ether 115-10-6 >= 1.0 - <= 5.
PAGE 14
Product Name: GREAT STUFF(TM) Big Gap Filler Insulating Foam Sealant 16oz HC STEL TWA ACGIH DOW IHG WEEL HAZ_DES Action Level Issue Date: 12/10/2012 Short Term Exposure Limit Time Weighted Average American Conference of Governmental Industrial Hygienists, Inc. Dow Industrial Hygiene Guideline Workplace Environmental Exposure Level Hazard Designation A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded.