SAFETY DATA SHEET THE DOW CHEMICAL COMPANY Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Print Date: 04/20/2016 THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Signal word: DANGER! Hazards Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause harm to breast-fed children.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Other hazards Water Reactive 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component CASRN Concentration Polymethylenepolyphenylisocyanate, propoxylated glycerin polymer 57029-46-6 >= 30.0 - <= 60.0 % Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 >= 10.0 - <= 30.0 % Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 5.0 - <= 10.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more effective than soap and water. Discard items which cannot be decontaminated, including leather articles such as shoes, belts and watchbands.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Dense smoke is produced when product burns. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 area. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Contents under pressure. Do not puncture or incinerate container. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Other protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Respiratory protection: Atmospheric levels should be maintained below the exposure guideline.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: No data available Chemical stability: Stable under recommended storage conditions. See Storage, Section 7. Unstable at elevated temperatures. Possibility of hazardous reactions: Can occur.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Acute inhalation toxicity In confined or poorly ventilated areas, vapor can easily accumulate and can cause unconsciousness and death due to displacement of oxygen. Excessive exposure may cause irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema (fluid in the lungs.) Effects may be delayed. May cause central nervous system depression.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only at high doses which were toxic to the mother. Reproductive toxicity Based on information for component(s): May cause harm to breastfed babies. Mutagenicity In vitro genetic toxicity studies were negative for component(s) tested. Genetic toxicity data on MDI are inconclusive.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000 mg/kg Toxicity to terrestrial plants EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l Tris(1-chloro-2-propyl) phosphate Acute toxicity to fish Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and 100 m
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Acute toxicity to algae/aquatic plants Based on information for a similar material: NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition, 1,640 mg/l, OECD Test Guideline 201 or Equivalent Toxicity to bacteria Based on information for a similar material: EC50, activated sludge, static test, 3 Hour, Respiration rates.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability. 10-day Window: Fail Biodegradation: 14 % Exposure time: 28 d Method: OECD Test Guideline 301E or Equivalent 10-day Window: Not applicable Biodegradation: 95 % Exposure time: 64 d Method: OECD Test Guideline 302A or Equivalent Theoretical Oxygen Demand: 1.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 4.4 d Method: Estimated. Propane Biodegradability: No relevant data found. Theoretical Oxygen Demand: 3.64 mg/mg Photodegradation Test Type: Half-life (indirect photolysis) Sensitizer: OH radicals Atmospheric half-life: 8.4 d Method: Estimated.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.76 Measured Propane Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient: n-octanol/water(log Pow): 2.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 In the aquatic and terrestrial environment, movement is expected to be limited by its reaction with water forming predominantly insoluble polyureas. 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. REGULATORY INFORMATION OSHA Hazard Communication Standard This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Product name: GREAT STUFF™ Big Gap Filler Insulating Foam Sealant 20oz HC ES 12ct Issue Date: 01/04/2016 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH Asphyxiant C NIOSH REL OSHA Z-1 STEL TWA US WEEL USA. ACGIH Threshold Limit Values (TLV) Asphyxiant Ceiling USA. NIOSH Recommended Exposure Limits USA.