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07/27/2016

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Buttergrade

Safety Data Sheet 4032

Revision Date: 07/27/2016 Date of issue: 02/29/2016

SECTION 1: IDENTIFICATION

1.1. Product Identifier

Product Form: Mixture

Product Name: Buttergrade

1.2. Intended Use of the Product

Use of the substance/mixture: Waterproof Spackling and Filling Compound

1.3. Name, Address, and Telephone of the Responsible Party

Company

GAF

1 Campus Drive

Parsippany, NJ 07054 USA

1-800–766–3411

Emergency Number :

CHEMTREC [DAY OR NIGHT] 1-800-424-9300

Outside USA and Canada: 1 703-741-5970

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the Substance or Mixture

GHS-US classification

Skin Sens. 1

H317

Aquatic Acute 3

H402

Aquatic Chronic 3

H412

Full text of H-phrases: see section 16

2.2. Label Elements

GHS-US Labeling

Hazard Pictograms (GHS-US)

GHS07

Signal Word (GHS-US)

Warning

Hazard Statements (GHS-US)

H317 - May cause an allergic skin reaction.

H402 - Harmful to aquatic life.

H412 - Harmful to aquatic life with long lasting effects.

Precautionary Statements (GHS-US)

P261 - Avoid breathing vapors, mist, or spray.

P272 - Contaminated work clothing must not be allowed out of the workplace.

P273 - Avoid release to the environment.

P280 - Wear protective gloves, protective clothing, and eye protection.

P302+P352 - If on skin: Wash with plenty of water.

P321 - Specific treatment (see section 4 on this SDS).

P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.

P363 - Wash contaminated clothing before reuse.

P501 - Dispose of contents/container in accordance with local, regional, national,

and international regulations.

2.3. Other Hazards

Exposure may aggravate pre-existing eye, skin, or respiratory conditions. If this product is allowed to dry and dust is generated,

inhalable fractions may contain hazardous ingredients listed in section 3 that may cause cancer, damage to organs through

prolonged or repeated exposure, and respiratory irritation.

2.4. Unknown Acute Toxicity (GHS-US)

No data available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1. Substance

Not applicable

3.2. Mixture

Name Product Identifier

GHS-US classification

Limestone (CAS No) 1317-65-3 5 - 40 Not classified

Summary of content (12 pages)

PAGE 1
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 SECTION 1: IDENTIFICATION 1.1. Product Identifier 1.2. Intended Use of the Product 1.3.
PAGE 2
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 Titanium dioxide Zinc oxide (CAS No) 13463-67-7 (CAS No) 1314-13-2 1 - 15 0.5 - 1.3 Co-solvent 1 Co-solvent 2 Quartz (CAS No) Proprietary (CAS No) Proprietary (CAS No) 14808-60-7 0.1 - 1 0.1 - 0.29 0.1 - 0.26 Dispersing agent (CAS No) Proprietary 0.05 - 0.23 Surfactant 1 (CAS No) Proprietary 0 .05 - 0.16 Silica, amorphous Biocide (CAS No) 7631-86-9 (CAS No) 26530-20-1 0.05 - .15 0.05 - 0.
PAGE 3
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 Full text of H-phrases: see section 16 The specific chemical identity and/or exact percentage of composition has been withheld as a trade secret within the meaning of the OSHA Hazard Communication Standard [29 CFR 1910.1200]. In the event of an emergency, chemical identities and exact percentages of the proprietary ingredients may need to be disclosed to emergency personnel upon request.
PAGE 4
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 6.4. Date of issue: 02/29/2016 Reference to Other Sections See Heading 8. Exposure controls and personal protection. See Section 13, Disposal Considerations. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling 7.2. Conditions for Safe Storage, Including Any Incompatibilities Precautions for Safe Handling: Do not handle until all safety precautions have been read and understood.
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Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 USA IDLH USA OSHA 8.2. Date of issue: 02/29/2016 US IDLH (mg/m³) OSHA PEL (TWA) (mg/m³) 500 mg/m³ 5 mg/m³ (fume) 15 mg/m³ (total dust) 5 mg/m³ (respirable fraction) Exposure Controls Appropriate Engineering Controls Personal Protective Equipment : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation, especially in confined areas.
PAGE 6
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 10.4. Conditions to Avoid: Direct sunlight, extremely high or low temperatures, and incompatible materials. 10.5. Incompatible Materials: Strong acids, strong bases, strong oxidizers. Anhydrides. Strong mineral acids. Reducing agents. 10.6. Hazardous Decomposition Products: Thermal decomposition generates: Carbon oxides (CO, CO2). Nitrogen oxides. Metal oxides. Amines. Hydrocarbons. Acrylates.
PAGE 7
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 Surfactant 2 (Proprietary) LD50 Dermal Rat > 2000 mg/kg Zinc oxide (1314-13-2) LD50 Oral Rat > 5000 mg/kg LD50 Dermal Rat > 2000 mg/kg Skin Corrosion/Irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory or Skin Sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Not classified Carcinogenicity: Not classified.
PAGE 8
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 EC50 Daphnia 1 LC 50 Fish 2 EC50 Daphnia 2 10000 mg/l (Exposure time: 24 h - Species: Daphnia magna) 41 - 47 ml/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) Co-solvent 3 (Proprietary) LC50 Fish 1 EC50 Daphnia 1 LC 50 Fish 2 41000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) 46300 mg/l (Exposure time: 48 h - Species: Da
PAGE 9
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 S - S - indicates a substance that is identified in a proposed or final Significant New Uses Rule.
PAGE 10
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 U.S. - Pennsylvania - RTK (Right to Know) List Silica, amorphous (7631-86-9) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Limestone (1317-65-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Quartz (14808-60-7) U.S.
PAGE 11
Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Date of issue: 02/29/2016 Comb. Dust Eye Dam. 1 Eye Irrit. 2A Eye Irrit. 2B Flam. Liq. 3 Flam. Liq. 4 Muta. 2 Org. Perox. F Skin Corr. 1B Skin Corr. 1C Skin Irrit. 2 Skin Sens. 1 Skin Sens. 1B STOT RE 1 STOT RE 2 STOT SE 3 H226 H227 Comb.
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Buttergrade Safety Data Sheet 4032 Revision Date: 07/27/2016 Revision Information 07/27/2016 Date of issue: 02/29/2016 damage that may occur from the use of this information. Nothing herein shall be construed as a recommendation for uses which infringe valid patents or as extending a license of valid patents. Conversion to GAF SDS.