Safety Data Sheets (SDS)

ManualsBrandsFROTH-PAK ManualsCaulks & Sealants200 Foam Sealant Kit

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SAFETY DATA SHEET

DDP Specialty Electronic Materials US,

LLC

Product name: Froth-Pak™ ISO HFO 200BF cylinder

Issue Date: 02/23/2021

Print Date: 06/29/2021

DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the

entire (M)SDS, as there is important information throughout the document. We expect you to follow

the precautions identified in this document unless your use conditions would necessitate other

appropriate methods or actions.

1. IDENTIFICATION

Product name: Froth-Pak™ ISO HFO 200BF cylinder

Recommended use of the chemical and restrictions on use

Identified uses: For industrial use. We recommend that you use this product in a manner consistent

with the listed use. If your intended use is not consistent with the stated use, please contact your sales

or technical service representative.

COMPANY IDENTIFICATION

DDP Specialty Electronic Materials US,

LLC

974 Centre Road, Building 730,

Wilmington DE 19805

UNITED STATES

Customer Information Number:

833-338-7668

SDSQuestion-NA@dupont.com

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 1-800-424-9300

Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION

Hazard classification

GHS classification in accordance with 29 CFR 1910.1200

Gases under pressure - Liquefied gas

Acute toxicity - Category 4 - Inhalation

Skin irritation - Category 2

Eye irritation - Category 2B

Respiratory sensitisation - Category 1

Skin sensitisation - Category 1

Specific target organ toxicity - single exposure - Category 3

Specific target organ toxicity - repeated exposure - Category 2 - Inhalation

Simple Asphyxiant

Label elements

Hazard pictograms

Summary of content (17 pages)

PAGE 1
SAFETY DATA SHEET DDP Specialty Electronic Materials US, LLC Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Print Date: 06/29/2021 DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Signal word: DANGER! Hazards Contains gas under pressure; may explode if heated. Causes skin and eye irritation. May cause an allergic skin reaction. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled. May displace oxygen and cause rapid suffocation.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder This product is a mixture. Component Issue Date: 02/23/2021 CASRN Concentration Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9 > 60.0 - <= 80.0 % 4,4' -Methylenediphenyl diisocyanate 101-68-8 > 20.0 - <= 40.0 % trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 > 0.0 - < 20.0 % Note Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. 4.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including pulmonary edema, may be delayed.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Isolate area. Keep unnecessary and unprotected personnel from entering the area. Refer to section 7, Handling, for additional precautionary measures. Keep personnel out of low areas. Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder trans-1-Chloro-3,3,3trifluoropropene US WEEL Issue Date: 02/23/2021 TWA 800 ppm Exposure controls Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Flash point Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight Issue Date: 02/23/2021 > 200 °C ( > 392 °F) Not available Not expected to form
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Hazardous decomposition products: Decomposition products depend upon temperature, air supply and the presence of other materials. Gases are released during decomposition. 11. TOXICOLOGICAL INFORMATION Toxicological information appears in this section when such data is available. Acute toxicity Acute oral toxicity Product test data not available. Refer to component data. Acute dermal toxicity Product test data not available.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Aspiration Hazard Product test data not available. Refer to component data. COMPONENTS INFLUENCING TOXICOLOGY: Diphenylmethane Diisocyanate, isomers and homologues Acute oral toxicity Typical for this family of materials. LD50, Rat, > 10,000 mg/kg Acute dermal toxicity Typical for this family of materials. LD50, Rabbit, > 9,400 mg/kg Acute inhalation toxicity LC50, Rat, 4 Hour, dust/mist, 0.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 LD50, Rat, > 2,000 mg/kg No deaths occurred at this concentration. Acute dermal toxicity LD50, Rabbit, > 9,400 mg/kg Acute inhalation toxicity LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l Skin corrosion/irritation Prolonged contact may cause moderate skin irritation with local redness. Repeated contact may cause moderate skin irritation with local redness. May stain skin. Serious eye damage/eye irritation May cause moderate eye irritation.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Sensitization Did not cause allergic skin reactions when tested in humans. For respiratory sensitization: No relevant data found. Specific Target Organ Systemic Toxicity (Single Exposure) Evaluation of available data suggests that this material is not an STOT-SE toxicant. Reproductive toxicity No relevant data found. Aspiration Hazard Based on available information, aspiration hazard could not be determined. 12.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l 4,4' -Methylenediphenyl diisocyanate Acute toxicity to fish The measured ecotoxicity is that of the hydrolyzed product, generally under conditions maximizing production of soluble species. Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 environment, material is expected to have a short tropospheric half-life, based on calculations and by analogy with related diisocyanates.
PAGE 14
Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 13. DISPOSAL CONSIDERATIONS Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator.
PAGE 15
Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 15.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 Revision Identification Number: 12074990 / A749 / Issue Date: 02/23/2021 / Version: 2.1 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend ACGIH C Dow IHG OSHA Z-1 STEL TWA US WEEL USA. ACGIH Threshold Limit Values (TLV) Ceiling Dow Industrial Hygiene Guideline USA.
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Product name: Froth-Pak™ ISO HFO 200BF cylinder Issue Date: 02/23/2021 DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above.